Functionalized surfaces based on metallic nanoparticles for optics and photonics

In this thesis, we have developed an experimental method based on the use of a continuous ultraviolet laser to process a soda-lime glass doped with either Ag+ or Au3+ ions for the growth of silver and/or gold nanoparticles (NP). The main advantage of method lies in the very high photosensitivity of the glass at the laser wavelength (244 nm), compared to the results of the literature. In silver-exchanged soda-lime glasses, highly concentrated silver NP of large diameter (up to 250 nm) have been obtained and their growth is fully elucidated. We have then shown that these substrates are well-suited to get efficient surface enhanced raman scattering effect with rhodamine 6G as test molecule, which was the first aim of this thesis. A third part is then dedicated to the growth of periodic nanostructures embedded with silver NP at the surface of the glass. Silver NP (of average diameter 80 nm) are aligned along lines periodically spaced by 160 nm. After experimental characterization of these periodic arrangements, we have demonstrated very good agreement between these experimental results and classical ripples theory (known as Sipe’s model in the literature).This result is undoubtedly the most original result of this manuscrit. We have then shown that laser exposure at 244 nm allows the growth of gold NP in soda-lime glass beforehand doped with Au3+ ions by thermal poling. Codoping of the glass containing with both silver and gold nanoparticles has also been achieved

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Source https://theses.hal.science/tel-00997367
Author Sow, Mohamed
Maintainer CCSD
Last Updated May 5, 2026, 10:05 (UTC)
Created May 5, 2026, 10:05 (UTC)
Identifier NNT: 2013STET4005
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire Hubert Curien (LabHC) ; Institut d'Optique Graduate School (IOGS)-Université Jean Monnet - Saint-Étienne (UJM) ; Université Jean Monnet (EPSCPE) (UJM EPE)-Université Jean Monnet (EPSCPE) (UJM EPE)-Centre National de la Recherche Scientifique (CNRS)
creator Sow, Mohamed
date 2013-06-06T00:00:00
harvest_object_id 370decfc-edf8-4e74-a39a-df5f76bc6962
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-04-23T00:00:00
set_spec type:THESE