Synthesis and characterisations of lead-free piezoelectric thin films

Industrial interest, political pressure: two major reasons for the synthesis of unleaded piezoelectric thin layers with high performances have become an important research topic. The objective of this work is the synthesis and characterization of a promising material: NBT. The development of NBT thin films by rf-magnetron sputtering was optimized. The study shows that annealing at 675°C under oxygen allows better crystallization of NBT. Electrical characterizations showed good dielectric, ferroelectric and piezoelectric properties. Polarization and displacement values obtained by applying an electric field are remarkable. However, values of remnant polarization are low. The temperature study was used to determine phase transitions and highlighted the relaxor character of NBT. The mixture of BT with the NBT in a solid solution should improve the electrical performances. Leakage currents caused the opposite effect, that is to say, a degradation of the properties of our thin films.

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Source https://theses.hal.science/tel-00985252
Author Quignon, Sébastien
Maintainer CCSD
Last Updated May 5, 2026, 12:40 (UTC)
Created May 5, 2026, 12:40 (UTC)
Identifier NNT: 2013VALE0038
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520 (IEMN) ; Centrale Lille-Institut supérieur de l'électronique et du numérique (ISEN)-Université de Valenciennes et du Hainaut-Cambrésis (UVHC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université Polytechnique Hauts-de-France (UPHF)
creator Quignon, Sébastien
date 2013-11-21T00:00:00
harvest_object_id cc2bc92f-b336-4332-bb30-b79f94235ad6
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-31T00:00:00
set_spec type:THESE