Thermal investigations on polymer dispersed liquid crystal composites and thermo-electric polymer composites using photothermal techniques

Primarily, newly developed, high sensitive and accurate methods for thermal characterization of liquids using photothermal radiometry are presented. Two experimental configurations are suggested, tested and validated with usual liquid materials. These methods are used to study polymer dispersed liquid crystal samples. Dynamic thermal properties of samples are analysed verses amplitude varying applied electric field with constant frequency as well as versus frequency varying electric field with constant amplitude. Our results clearly show the thermal properties of the samples are prone to depolarizing field effects at the lower frequencies of the applied electric field. The experimental results are modeled against existing theories to predict electric properties of the sample composites. Second part of the manuscript describes the development of a novel photothermal technique based on thermoelectric effect. This technique is particularly useful for thermally characterizing thermoelectric materials without using a separate sensor for measuring induced temperature changes. A theoretical and experimental study is presented. The experiments are done on polyaniline - carbon nanotube composite pellets by measuring Seebeck voltage generated by the samples upon heating by a modulated laser beam. Additional infrared radiometry experiments are done on the same samples and the results are in good agreement with those previously found. Later on, the possibility of photothermoelectric materials to be used as sensors for finding thermal transport properties of materials with a thermal wave resonant cavity is suggested.

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Source https://theses.hal.science/tel-00982712
Author Kuriakose, Maju
Maintainer CCSD
Last Updated May 5, 2026, 13:25 (UTC)
Created May 5, 2026, 13:25 (UTC)
Identifier NNT: 2013DUNK0319
Language en
Rights https://about.hal.science/hal-authorisation-v1/
contributor Unité de Dynamique et Structure des Matériaux Moléculaires (UDSMM) ; Université du Littoral Côte d'Opale (ULCO)-Université de Lille
creator Kuriakose, Maju
date 2013-06-26T00:00:00
harvest_object_id ea1617c5-6668-4db4-a4e9-e3aff6e01066
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-31T00:00:00
set_spec type:THESE