Polymer solution flows : links between microscopic properties and macroscopic behaviors

This work considers the interaction between a flow field and the microscopic degrees of a freedom of a polymer solution. Different flow configurations were considered.Droplet pinch off, which occurs when a drop of liquid detaches from a capillary, can be strongly modified in the presence of polymers giving rise to long and slender filaments that thin slowly in time. We here study experimentaly the dynamics of necking and the conformations of polymers during the thinning of the neck. Our results show that the slow down of the thinning dynamics is the result of polymer stretching. Moreover, during the filament thinning, the polymer length distribution remains the same. This result is unexpected and led us to introduce a new method to estimate the extensionnal viscosity which represents the polymer solution resistance to stretching.In a second flow configuration, we have observed that depletion of polymer molecules near a surface occurs when a bead approaches a plate in a polymer solution.

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Source https://theses.hal.science/tel-00912345
Author Ingremeau, François
Maintainer CCSD
Last Updated May 8, 2026, 00:20 (UTC)
Created May 8, 2026, 00:20 (UTC)
Identifier NNT: 2013BOR14874
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire Ondes et Matière d'Aquitaine (LOMA) ; Université de Bordeaux (UB)-Centre National de la Recherche Scientifique (CNRS)
creator Ingremeau, François
date 2013-10-21T00:00:00
harvest_object_id 19f94cc6-3396-458f-8c44-88909f87c91e
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-31T00:00:00
set_spec type:THESE