Crystallization and heat transfer in a semi-crystalline thermoplastic polymer under pressure and high cooling rate

An accurate description of the heat transfer is essential in the simulation and optimization of processes, the quality of semicrystalline thermoplastic parts is strongly linked to the thermal history during the formatting. Reliable results require a fine knowledge of the thermophysical properties of the polymer. The objective of this work is to develop experimental devices associated with identification methods to measure the thermal properties and crystallization kinetics of polymer under the material forming conditions. A measurement protocol and the identification of thermal properties and crystallization kinetics of polypropylene by inverse methods under low pressure and low cooling rate has been developed in a first study. Then, a new PvT device running up to 400 ° C and 200 MPa has been designed and experimentally validated. The thermal conductivity and the crystallization kinetics were measured under high cooling rate and high pressure. A luminance sensor combining an optical fiber and a photodetector has been set up on a device of the laboratory in order to measure the surface temperature of a polypropylene and thus to identify its crystallization kinetics under high cooling rate. The sensor has been experimentally calibrated and validated. The last part deals with the thermoplastic injection process by presenting a methodology for identifying the kinetics of crystallization from the pressure measurement.

Data and Resources

Additional Info

Field Value
Source https://theses.hal.science/tel-00880924
Author Tardif, Xavier
Maintainer CCSD
Last Updated May 9, 2026, 03:01 (UTC)
Created May 9, 2026, 03:01 (UTC)
Identifier tel-00880924
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire de thermocinétique [Nantes] (LTN) ; Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)
creator Tardif, Xavier
date 2012-10-22T00:00:00
harvest_object_id e24aa0e7-3b03-41c0-b5c7-6e3643795c15
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-31T00:00:00
set_spec type:THESE