Relationship structure/ elongational thermomechanical behavior of thermoplastic polymer films

The work presented in this manuscript is devoted to the modeling of the thermomechanicalbehavior of polymer films deformed at the rubbery state. The modeling of the isotropicamorphous films is realized using the Lodge and the MSF models. For deformations appliednear the glass transition temperature, the predictions of these models are improved byincluding relaxation times coming from the glass transition domain in the spectra. Forpre-oriented amorphous films, the anisotropy is modeled by considering that it is due to aprevious equivalent deformation during the fabrication process.The relationship between the crystalline phase and the mechanical behavior at roomtemperature for the semi-crystalline films is established. During the deformation at therubbery sate of the semi-crystalline films, a reorientation of the crystalline phase occurs alongthe stretching direction. Based on the experimental observations, a semi-empirical model isdeveloped in order to describe the mechanical behavior of the semi-crystalline films. In thismodel, the contributions of both phases, amorphous and crystalline are separated. Thereorientation of the crystalline phase leads to a strain hardening stage which could bepredicted by the model

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Source https://theses.hal.science/tel-00871322
Author Thevenon, Anthony
Maintainer CCSD
Last Updated May 9, 2026, 10:35 (UTC)
Created May 9, 2026, 10:35 (UTC)
Identifier NNT: 2012LYO10020
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Ingénierie des Matériaux Polymères (IMP) ; Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon) ; Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Université Jean Monnet - Saint-Étienne (UJM) ; Université Jean Monnet (EPSCPE) (UJM EPE)-Université Jean Monnet (EPSCPE) (UJM EPE)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
creator Thevenon, Anthony
date 2012-02-14T00:00:00
harvest_object_id 873d5558-ea09-4088-9683-6507b58518dc
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-04-23T00:00:00
set_spec type:THESE