Multi-scale characterisation of the bearing phases of the metallic pollutants Zn and Pb in a deposited sediment : from field studies to synchrotron radiation analysis

Sediments originating from periodic dredging of waterways were traditionally deposited on soil without specific precaution or planed treatments. It may be of environmental concern especially when they came from areas historically contaminated with metallic pollutants like in the north French coal basin which is also well industrialised. The main risk is a migration Metallic Trace Elements (MTE) in the underlying soil and groundwater. This study aims to identify and characterise the mineralogical bearing phases of the MTE (limited here to Zn et Pb) by combining various techniques, analytical, chemical and spectroscopic. In this work, we show that in the case of a complex material as our studied anthroposol, it is important to have a multi-scale. Then, we have carried out field analyses, laboratory studies Sequential chemical extraction, XRD, SEM and EPMA) and synchrotron radiation experiment (mainly XRF and XANES). We have indentified various bearing phases of Zn and Pb, but we didn’t observe any clear evolution as a function of the depth. To conclude, we give several directions for completing this work.

Data and Resources

Additional Info

Field Value
Source https://theses.hal.science/tel-00840257
Author Poitevin, Antonine
Maintainer CCSD
Last Updated May 10, 2026, 12:24 (UTC)
Created May 10, 2026, 12:24 (UTC)
Identifier NNT: 2012ORLE2061
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI) ; Université d'Orléans (UO)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
creator Poitevin, Antonine
date 2012-11-29T00:00:00
harvest_object_id a26790b0-95d1-4d3e-afa8-038bb32cbba3
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-31T00:00:00
set_spec type:THESE