This thesis presents some results in quantum probability and operator-valued harmonicanalysis. The main results obtained in the thesis are contained in the following three parts:In first part, we prove the atomic decomposition for the Hardy spaces h1 and H1 of noncommutative martingales. We also establish that interpolation results on the conditionedHardy spaces of noncommutative martingales. The second part is devoted to studying operator-valued Hardy spaces via Meyer’s wavelet method. It turns out that this way of approaching these spaces is parallel to that in the noncommutative martingale case. We also show that these Hardy spaces coincide with those introduced and studied by Tao Mei in [52]. As a consequence, we give an explicit completely unconditional base for Hardy spaces H1(R) equipped with a natural operator space structure. The third part deals with with harmonic analysis on quantum tori. We first establish the maximal inequalities for several means of Fourier series defined on quantum tori and obtain the corresponding pointwise convergence theorems. In particular, we prove the noncommutative analogue of the classical Stein theorem on Bochner-Riesz means. Then we prove that Lp completely bounded Fourier multipliers on quantum tori coincide with those on classical tori with equal cb-norms. Finally, we present the H1-BMO and Littlewood- Paley theories associated with the circular Poisson semigroup over quantum tori.