Combined ²H NMR and neutron spectroscopy study of dynamics of adsorbed species in porous materials

The work is dedicated to the investigation of dynamics of molecular species confined in nano-meso porous media. To investigate the translational diffusion, quasielastic neutron scattering technique was used. To characterize the rotational dynamics and intramolecular dynamics of the confined species, solid state 2H NMR was used. Several systems were studied : (i) dynamics of water in selective water sorbent SWS-1L based on CACL2 salt and porous silica ; (ii) dynamics of linear alkanes confined in zeolite 5A pores ; (iii) dynamics of linear butane in zeolite ZSM-5 ; (iv) dynamics of benzene rings in the metal-organic frameworks MIL-53 and MIL-47 ; (v) dynamics of hydrogen in MILs47 and 53. In all cases, the dynamics and the state of adsorbed species were characterized and it was shown that the dynamics in confinement strongly deviates from the dynamics in the usual bulk state.

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Source https://theses.hal.science/tel-00833374
Author Kolokolov, Daniil
Maintainer CCSD
Last Updated May 10, 2026, 18:13 (UTC)
Created May 10, 2026, 18:13 (UTC)
Identifier NNT: 2010LYO10102
Language ru
Rights https://about.hal.science/hal-authorisation-v1/
contributor Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON) ; Université Claude Bernard Lyon 1 (UCBL) ; Université de Lyon-Université de Lyon-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
creator Kolokolov, Daniil
date 2010-06-23T00:00:00
harvest_object_id 1af829bb-f69b-4d82-8eef-da785f31bdd8
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-04-17T00:00:00
set_spec type:THESE