Contribution to the determination of the vapour pressure curve of pure water in the temperature range between -80 ° C to +100 ° C, with high accuracy

The determination of the physical properties of pure water, especially the vapor-pressure curve, is one of the major issues identified by the Consultative Committee for Thermometry (CCT) of the technical committee in thermometry sub-field hygrometry to improve the accuracy of the national references in humidity.In order to achieve this objective, the LNE-CETIAT and the LNE-Cnam have jointly built a facility dedicated to the measurement of the saturation vapor pressure and temperature of pure water. The principle is based on a static measurement of the pressure and the temperature of pure water in a closed, temperature-controlled thermostat, conceived like a quasi-adiabatic calorimeter. The explored temperature range lies between 193,15 K and 373,15 K, and the pressure range between 0,06 Pa and 105 Pa.This work presents a full description of this facility and the preliminary results obtained for its characterization. The obtained results have been compared with available literature data. The final uncertainty budget took into account several components: pressure measurements, temperature measurements and environmental error sources such as thermal transpiration and hydrostatic pressure correction. Thanks to the employment of several technical solutions, the thermal contribution to the overall uncertainty budget is reduced, and the remaining major part is mainly due to pressure measurements.

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Source https://theses.hal.science/tel-00770987
Author Mokdad, Sid-Ali
Maintainer CCSD
Last Updated May 15, 2026, 12:49 (UTC)
Created May 15, 2026, 12:49 (UTC)
Identifier NNT: 2012CNAM0825
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire commun de métrologie LNE-CNAM (LCM-CNAM) ; Laboratoire National de Métrologie et d'Essais [Trappes] (LNE)-Conservatoire National des Arts et Métiers [Cnam] (Cnam)
creator Mokdad, Sid-Ali
date 2012-09-28T00:00:00
harvest_object_id 72896abe-c60f-4981-ba92-176d9fbeee9f
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-30T00:00:00
set_spec type:THESE