Study of a long term solar thermal energy storage based on LiBr−H2O for house heating

Energy storage is a key component to improve the efficiency of energy systems, especially when the energy source is intermittent, such as solar energy. Heat storage systems based on sorption processes are relevant in case of long-term storage (seasonal or pluriannual storage) because of their acceptable heat losses. Even though considerable breakthroughs have been made in the past decades, there is no mature long-term sorption heat storage yet. The aim of this work is to demonstrate the feasibility of a long term solar thermal storage by absorption for building space heating. Solar heat is stored in summer using desorption process and released in winter via absorption. A multicriteria analysis on various possible absorption couples leads to the choice of LiBr−H2O as storage media for the concept feasibility demonstration. It has been shown that crystallisation in the solution storage tank can increase the storage density by three times and therefore, is relevant for the process competiveness. A dynamic model has been developed for the system design and simulations under various operating conditions were performed. A lot of parametric simulations are used to investigate the influence of certain parameters and controls aspects. This helps designing a demonstrative prototype that can store 8 kWh of heat and can produce a heating power of 1 kW. The prototype has been built and tested on a test bed in static and dynamic operating conditions that are compatible with domestic solar thermal plants. The charging process has been proved successful. Absorption during discharging phase is also verified. However, some problems related to the absorber design have not made possible to observe the heat release as expected. Various aspects such as stratification and circulation in the solution storage tank have also been addressed. The model comparison with experimental result is then performed and discussed.

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Source https://theses.hal.science/tel-00710249
Author N’tsoukpoe, Kokouvi Edem
Maintainer CCSD
Last Updated May 15, 2026, 15:09 (UTC)
Created May 15, 2026, 15:09 (UTC)
Identifier NNT: 2012GRENA005
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor LabOratoire proCédés énergIe bâtimEnt (LOCIE) ; Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)
creator N’tsoukpoe, Kokouvi Edem
date 2012-03-19T00:00:00
harvest_object_id c5aaa592-e3c2-45ac-975a-701ba4e93112
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-30T00:00:00
set_spec type:THESE