Study of release mechanisms of entrapped additives, application to well treatment

Many thermodynamic changes occur in reservoir rock when oil is produced. These changes enable scale formation on micrometric rock pores that can block them and impede/block oil extraction. Antiscale treatment efficiency depends on minimal inhibitor concentration and product release rate in fluids downhole. In this context, we have studied two encapsulation techniques allowing us to have a sustainable release system composed of an anionic polyelectrolyte as a model additive. The first formulation consists in formation of polyelectrolyte complexes nanoparticles. In this system, active ingredient release was stimulated through medium ionic strength modulation. Under basic conditions, release takes place in particles swelling/dissociation process; whereas, under acidic condition, particles precipitate and no release can be expected. The second system we have worked on is a diluted reverse (W/O) emulsion, in which dispersed aqueous droplets contain a model additive. These systems are stable and small additive percentage is released under mechanic strain.

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Source https://theses.hal.science/tel-00704308
Author Rondon, Céline
Maintainer CCSD
Last Updated May 16, 2026, 04:02 (UTC)
Created May 16, 2026, 04:02 (UTC)
Identifier tel-00704308
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Transferts, écoulements, fluides, énergétique (TREFLE) ; Université Sciences et Technologies - Bordeaux 1 (UB)-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Centre National de la Recherche Scientifique (CNRS)
creator Rondon, Céline
date 2010-12-14T00:00:00
harvest_object_id 4cc3cb99-02e5-4520-b0b2-318a3cd2464f
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-04-22T00:00:00
set_spec type:THESE