Study on the nanostructuration influence on corrosion behavior of multilayer PVD coatings

This work is part of an ANR project which purpose is to find an alternative to sacrificial electrolytic coatingsusing aluminium-based PVD coatings, which are more environmental friendly. Three main parameters weredefined : a sacrificial behavior, good tribological properties and the possibility to elaborate the coatings before shaping the steel substrate. Monolayer coatings were elaborated to study the impact of an alloying element on aluminium properties. Some alloying elements increase mechanical properties (Mo, Mn) while others enhance the electrochemical behavior (Mg, Zn). To combine both properties, two methods can be used. Either the elaboration ofternary alloys or the elaboration of multilayer coatings. This work is focused on the second way. Some multilayercoatings were proposed with two types of layers, each type presenting one interesting property. This study permitted to find a multilayer architecture fitting very well two parameters required for the project.A preliminary study on this architecture was lead with electrochemical characterization after strain. The architecture loses its sacrificial behavior after 1% strain in 48h immersion. Two of the three requested criteria are found.The next step of this work would be the optimization of the process parameters to enhance the adhesion of the coating so the third parameter is achieved.

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Source https://theses.hal.science/tel-00697016
Author Perez, Andréa
Maintainer CCSD
Last Updated May 18, 2026, 23:31 (UTC)
Created May 18, 2026, 23:31 (UTC)
Identifier NNT: 2011LAROS334
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire d'Etude des Matériaux en Milieux Agressifs (LEMMA) ; La Rochelle Université (ULR)
creator Perez, Andréa
date 2011-10-21T00:00:00
harvest_object_id ee07e22a-c483-4d89-b083-3a587c4a979a
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-30T00:00:00
set_spec type:THESE