Electrode biomaterials employed in fabrication and characterization of immunosensor and enzymatic biofuel cells.

This work is focused on the development of an impedimetric immunosensor and two enzymatic biofuel cells. Firstly, poly(pyrrole-NHS) is used to graft a model of the ciprofloxacin antibiotic (CF) and its specific antibody (Ab) in two steps. The displacement of the antibody in solution directed by a strong affinity between Ab and CF is monitored by electrochemical impedance spectroscopy. The detection limit is 10-12 g mL-1. Secondly, production of electricity is studied by two different methods. The first one is based on the creation of a pH difference driven enzymatically by glucose oxidase (GOx) and urease. This pH gradient is converted to e.m.f. by adding a pH-dependant redox couple. The second method uses glucose/O2 fu

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Source https://theses.hal.science/tel-00690367
Author Giroud, Fabien
Maintainer CCSD
Last Updated May 21, 2026, 01:40 (UTC)
Created May 21, 2026, 01:40 (UTC)
Identifier NNT: 2011GRENI048
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Département de Chimie Moléculaire (DCM) ; Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
creator Giroud, Fabien
date 2011-10-27T00:00:00
harvest_object_id fd9b7f58-e45c-4459-b10f-21074a98a287
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2026-03-30T00:00:00
set_spec type:THESE