In industry, to limit the number of experimental models in R&D projects, to better understand and to well interpret the complex ultrasonic phenomena observed du ring controls on site, simulations of ultrasonic controls are carried out. These simulations are all the more realistic as the description of structures to control is accurate, especially in terms of elastic constants, and intrinsic attenuation. The objectives of this study are firstly to improve knowledge about the influence of the metallurgical properties of anisotropie and heterogeneous materials on the ultrasonic propagation and secondly the performance of the computation codes (software ATHENA EDF) which need to have the relevant inputs, particularly as regards the elastic constants and ultrasonic attenuation. This study is dedicated to the characterization of coarse materials such as austenitic-ferritic steel centrifugally cast and the welding in steel austenitic stainless or in alloy nickel-based. A unique experimental system for measuring the elastic constants and attenuation at oblique incidence has been developed. The strong point of this device is that it can work beyond the longitudinal critical angle and thus to measure the attenuation properties of transversal waves. The elastic constants are deduced from ultrasonic speed from an optimization process based on the resolution of Inverse problems. We have shown the potential of global optimization algorithms such as genetic algorithms Jess likely to converge to local minima of the function to minimize. The results obtained from experimental measurements are in agreement with literature. Results of the attenuation of the longitudinal and transverse waves by beam decomposition into spectrum of plane waves are represented.