Elaboration and study of the electrical properties of an aligned carbon nanotubes - epoxy composite

This study presents first the fabrication of a composite material based on Multi-Walled Carbon Nanotubes (MWNT/CNT) synthesised by an aerosol-assisted Catalytic Chemical Vapour Deposition (CCVD) process into continuous and verticaly aligned carpets, and on an epoxy polymer matrix. Then the characterisation of the material's structure and surface is described. And then, its electrical transport properties are studied. The electrical conduction at room temperature is measured. First, locally by a Current-Sensing AFM (CS-AFM) so that the CNTs are characterized at an individual scale. Then, at the macroscopic scale, so that the material's properties are characterized when its size is easy at use. This study shows that the resistivity is low and anisotropic. Significant fluctuations (approximatively by a factor 10) in the macroscopic resistance exist from one measurement to an other. The nature of these fluctuations is discussed. The electrical conduction at low temperature (from 4 to 50◦K) displays at a macroscopic scale the same mesoscopic electric transport properties than individual CNTs. In particular, a conductance scaling law in function of the temperature and the voltage ("Zero Bias Anomaly") has been observed, as well as a weaklocalization (WL) law. Moreover, the conductance distribution measured by CS-AFM allows to demonstrate this persistence's origin with a simple and realistic model.

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Source https://pastel.hal.science/pastel-00794345
Author Roussel, Florent
Maintainer CCSD
Last Updated May 14, 2026, 04:19 (UTC)
Created May 14, 2026, 04:19 (UTC)
Identifier pastel-00794345
Language fr
Rights https://about.hal.science/hal-authorisation-v1/
contributor Laboratoire Francis PERRIN (LFP - URA 2453) ; Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Centre National de la Recherche Scientifique (CNRS)
creator Roussel, Florent
date 2012-03-30T00:00:00
harvest_object_id 4b22c8ea-066e-46ab-982a-c5830f556b4b
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2025-08-20T00:00:00
set_spec type:THESE