In \cite{cartier2}, Pierre Cartier conjectured that for any non commutative formal power series $\Phi$ on $X={x_0,x_1}$ with coefficients in a $\Q$-extension, $A$, subjected to some suitable conditions, there exists an unique algebra homomorphism $\varphi$ from the $\Q$-algebra generated by the convergent polyzêtas to $A$ such that $\Phi$ is computed from $\Phi_{KZ}$ Drinfel'd associator by applying $\varphi$ to each coefficient. We prove $\varphi$ exists and it is a free Lie exponential over $X$. Moreover, we give a complete description of the kernel of polyzêta and draw some consequences about a structure of the algebra of convergent polyzêtas and about the arithmetical nature of the Euler constant.