A Novel Synthesis of Deactivated Benzylic Triflones

A two-step synthesis of benzylic triflones, based on the reaction of 2,4,6-trisubstituted phenyl halides 3a-f with the anion of ethyl (trifluoromethanesulfonyl)acetate 1 followed by a decarboxylation reaction, is reported. The structural assignments are supported by spectroscopic data.

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Additional Info

Field Value
Source ISSN: 0039-7881
Author Tordeux, Marc, Goumont, Régis, Faucher, Nicolas, Moutiers, Gilles, Wakselman, Claude
Maintainer CCSD
Last Updated May 6, 2026, 05:39 (UTC)
Created May 6, 2026, 05:39 (UTC)
Identifier hal-00095238
Language en
contributor Synthèse, interactions et réactivité en chimie organique et bioorganique (SIRCOB) ; Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)
creator Tordeux, Marc
date 1997-05-06T00:00:00
harvest_object_id 5b6154ad-e387-4139-a493-c5034bff64e6
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2023-03-24T00:00:00
relation info:eu-repo/semantics/altIdentifier/doi/10.1055/s-1997-1390
set_spec type:ART