Superconductivity from doping Boron icosahedra.

We propose an alternative route to achieve the superconducting state in boron-rich solids, the hole doping of B12 icosahedra. For this purpose we consider a prototype metallic phase of B13C2. We show that in this compound the boron icosahedral units are mainly responsible for the large phonon frequencies logarithmic average, 65.8 meV, and the moderate electron-phonon coupling lambda= 0.81. We suggest that this high Tc could be a general feature of hole-doped boron icosahedral solids. Moreover our calculated moderate value of lambda excludes the formation of bipolarons localized on the icosahedral length scale as suggested by previous authors.

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Source ISSN: 1098-0121
Author Calandra, Matteo, Vast, Nathalie, Mauri, Francesco
Maintainer CCSD
Last Updated May 9, 2026, 20:24 (UTC)
Created May 9, 2026, 20:24 (UTC)
Identifier hal-00085907
Language en
contributor Laboratoire de minéralogie, cristallographie de Paris (LMCP) ; Université Pierre et Marie Curie - Paris 6 (UPMC)-Université Paris Diderot - Paris 7 (UPD7)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS)
creator Calandra, Matteo
date 2004-05-09T00:00:00
harvest_object_id cc9e6f36-5a30-4061-83c6-2cc093f452b1
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2025-07-15T00:00:00
relation info:eu-repo/semantics/altIdentifier/arxiv/cond-mat/0312200
set_spec type:ART