Electron paramagnetic resonance study of iridium in forsterite.

Electron paramagnetic resonance of Ir2+ in forsterite is studied at Q-band frequency and room temperature. There are four equivalent spectra superimposed along the three crystallographic axes. The individual spectrum consists of four hyperfine lines of approximately equal intensity separated from each other by 42 G; one axis of the g tensor is near the c axis. Ir2+ is certainly substituted for Mg2+. Because of the fourfold degeneracy of the EPR spectrum, it may be suggested that iridium occurs at M1. Taking into account that one eigenvector of the g tensor is nearly parallel to c, it seems also possible that the substitution takes place at the M2 position. In this case, the lattice relaxation of the crystal structure around Ir2+ at M2 must break the point symmetry m at M2.

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Source ISSN: 0342-1791
Author Gaite, Jean-Michel, Rager, H.
Maintainer CCSD
Last Updated May 19, 2026, 19:53 (UTC)
Created May 19, 2026, 19:53 (UTC)
Identifier hal-00069478
Language en
contributor Institut des Sciences de la Terre d'Orléans (ISTO) ; Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)
creator Gaite, Jean-Michel
date 2003-05-19T00:00:00
harvest_object_id ba65a688-e8db-4e7e-82b9-26fe512c4f7c
harvest_source_id 3374d638-d20b-4672-ba96-a23232d55657
harvest_source_title test moissonnage SELUNE
metadata_modified 2024-12-02T00:00:00
relation info:eu-repo/semantics/altIdentifier/doi/10.1007/s00269-003-0360-0
set_spec type:ART