@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:description """
              The use of copper and iron complexes as cross-coupling catalysts is now a challenge in today organic synthesis, due to their low cost and low toxicity. This work, in a first part, deals with mechanistic insights into C-N and C-O cross-couplings catalyzed by copper complexes. In a second part, the true role of iron in C-N cross-couplings processes is investigated. In a third part, two examples of iron-catalyzed C-C bond formations are investigated: a Kochi-type coupling between an aryl halide and a Grignard reagent, and a radical carbocyclization. Cyclic voltammetry, theoretical DFT calculations, NMR and EPR spectroscopies have been used as investigation tools.
            """ ;
    dct:identifier "NNT: 2012PAO66236" ;
    dct:issued "2026-05-10T18:14:41.418584"^^xsd:dateTime ;
    dct:language "fr" ;
    dct:modified "2026-05-10T18:14:41.418589"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "Mechanistic investigations of coupling reactions catalyzed by cooper and iron complexes" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
    dcat:distribution <https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-tel-00833319v1/resource/12b3a7f9-43b6-43a6-b1f4-17b28fd12b28> ;
    dcat:keyword "catalyse",
        "chimorgachemical-sciencesorganic-chemistry",
        "couplage-croise",
        "cuivre",
        "fer",
        "infoeu-reposemanticsdoctoralthesis",
        "modelisations-dft",
        "theses",
        "voltammetrie-cyclique" ;
    dcat:landingPage <https://theses.hal.science/tel-00833319> .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-tel-00833319v1/resource/12b3a7f9-43b6-43a6-b1f4-17b28fd12b28> a dcat:Distribution ;
    dct:format "HTML" ;
    dct:issued "2026-05-10T18:14:41.420404"^^xsd:dateTime ;
    dct:modified "2026-05-10T18:14:41.405594"^^xsd:dateTime ;
    dct:title "Mechanistic investigations of coupling reactions catalyzed by cooper and iron complexes" ;
    dcat:accessURL <https://theses.hal.science/tel-00833319> .

<https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> a foaf:Agent ;
    foaf:name "test_moissonnage_selune" .

<https://theses.hal.science/tel-00833319> a foaf:Document .