From classical polymerisations in solution towards radio-induced polymerisations controlled in confined space
type: Dataset
description: The manuscript of Mrs Marie-Claude Dubois-Clochard reports on the main results obtained in synthesis and structuration of functional polymers at the nanoscale. If the synthesis of functional polymers is the basic of the presented studies, the chronological order of her research activities from 1995 to 2013 shows an evolution from classical polymerisations in solution towards radio-induced polymerisations in confined space controlled by RAFT mechanism. The innovation is about the development of new objects made of polymers and organic/inorganic composites designed at the nanoscale to bring original physical and physico-chemical properties. Three applied fields stand out: Energy-Environment (Engines, Fuel cells, Sensors for water quality), Health (Nanovector for tumour therapies and imaging, Ion and molecules tranlocation through a single nanopore in a polymer membrane) and Nanotechnologies (Magnetoresistance of a single magnetic nanowire). Noteworthy results are: - the setting up of bi-langmuirian adsorption isotherm equations at solid/hydrocarbon interface for macromolecules at low concentrations, and, at high concentration, particular behaviour of reorganisation of these identical macromlecules, not in alternative layers but in reverse hemi-micelles formation. - the synthesis of a novel pH-dégradable polymer allowing an hydrolytic degradation from pH 7.4 (Sang) to pH 5.5 (Intracellular lysosome) to deliver drugs into tumor cells (Santé). - the radiation-induced grafting-through process in solid polymers showed by a cooperative effect of solvent/growing polymer chains into fluoropolymers. - the synthesis of bi-functional nanoporous polymer track-etched membranes having a functionality in the pores and another on the surface. This membrane, after changing in electrode by simple metallisation, has been the subject of valorisation projects to a start-up creation and/or a technological transfer for the development of a sensor able to detect heavy metals ions traces in t…
issued: 2026-05-11T02:47:03.429017
language: fr
modified: 2026-05-11T02:47:03.429022
contact point: Organization
  fn: CCSD
keyword: capteurs
keyword: chimpolychemical-sciencespolymers
keyword: fuel-cell
keyword: habilitation-a-diriger-des-recherches
keyword: infoeu-reposemanticsother
keyword: irradition-aux-ions-lourds-rapides
keyword: magnetoresistance
keyword: membranes-a-traces
keyword: nanopores
keyword: nanovecteurs
keyword: nanovectors
keyword: pile-a-combustible
keyword: polymerisation-radicalaire
keyword: radical-polymerisation
keyword: radiografting
keyword: radiogreffage
keyword: sensors
keyword: swift-heavy-ions-irradiation
keyword: track-membranes
landing page: https://theses.hal.science/tel-00823555

From classical polymerisations in solution towards radio-induced polymerisations controlled in confined space
type: Distribution
format: HTML
issued: 2026-05-11T02:47:03.437204
modified: 2026-05-11T02:47:03.409325
access URL: https://theses.hal.science/tel-00823555

test_moissonnage_selune
type: Agent