@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:description """
              RAFT-mediated controlled free-radical polymerization has been developed in an oil surfactant-free dispersed system: this system involves the dispersion polymerization of methyl acrylate in isododecane using soluble macromolecular RAFT agents (poly(2-ethylhexyl acrylate)) based either on a dithiobenzoate reactive group or on a trithiocarbonate one. The conditions to find a good control over the polymer chain growth together with formation of well-defined, self-stabilized particles have been examined. The process takes advantage of the in situ formation of amphiphilic block copolymers that self-assemble simultaneously with the growth step to form block copolymer micelles. The reactions are performed in very simple conditions, at high concentration and with a limited number of reactants. The comparison of the two systems, together with a detailed 2D chromatography characterization of the block copolymers enabled us to propose a mechanism. It appears that the quality of control over both the macromolecular structure and the colloidal characteristics strongly depends on the reactivity of the macroRAFT agent and its solvophilic/solvophobic character.
            """ ;
    dct:identifier "NNT: 2008PA066604" ;
    dct:issued "2026-05-11T13:10:55.674814"^^xsd:dateTime ;
    dct:language "fr" ;
    dct:modified "2026-05-11T13:10:55.674819"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "RAFT dispersion polymerization in organic medium : synthesis of block copolymers and simultaneous self-assembly" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
    dcat:distribution <https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-tel-00812126v1/resource/9c01d40a-9f7e-49a3-afb9-75410568eff1> ;
    dcat:keyword "acrylates",
        "auto-assemblage",
        "chiminorchemical-sciencesinorganic-chemistry",
        "copolymeres-a-blocs",
        "dispersion",
        "infoeu-reposemanticsdoctoralthesis",
        "no-data",
        "polymerisation-radicalaire-controlee",
        "raft",
        "theses" ;
    dcat:landingPage <https://theses.hal.science/tel-00812126> .

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    dct:format "HTML" ;
    dct:issued "2026-05-11T13:10:55.700413"^^xsd:dateTime ;
    dct:modified "2026-05-11T13:10:55.657675"^^xsd:dateTime ;
    dct:title "RAFT dispersion polymerization in organic medium : synthesis of block copolymers and simultaneous self-assembly" ;
    dcat:accessURL <https://theses.hal.science/tel-00812126> .

<https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> a foaf:Agent ;
    foaf:name "test_moissonnage_selune" .

<https://theses.hal.science/tel-00812126> a foaf:Document .