@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:description """
              Over the past decade, some (rare) examples of block copolymers with supramolecular links between the building blocks have been described. Because the association between macromolecular blocks is a reversible process, such polymers are of great interest in the field of nanostructured materials, self-healing materials, or processing aid. The main goal of this work is to develop new supramolecular architectures, by a combination of RAFT polymerization and H-bonding. In a first step, several chain transfer agents and a radical initiator possessing complementary thymine or diaminopyridine H-bonding moeties were synthesized. These precursors were used to generate a panel of polymers α- or α,ω-functionalized with these H-bonding stickers in a quantitative manner. The self-assembly of the resulting polymer blocks was highlighted by 1H NMR, AFM and rheological measurements. This approach was subsequently adapted to the development of hydrophilic supramolecular comb-shaped polymers, based on the β-cyclodextrin/adamantane host/guest complexation.
            """ ;
    dct:identifier "NNT: 2011ISAL0157" ;
    dct:issued "2026-11-01T20:34:55.997431"^^xsd:dateTime ;
    dct:language "fr" ;
    dct:modified "2026-11-01T20:34:55.997439"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "Design of functionalized chain transfer agents, precursors to supramolecular copolymers based on H-bonding and host/guest inclusion" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
    dcat:distribution <https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-tel-00735755v1/resource/de6eee04-478b-46a2-add0-3389d9db09e6> ;
    dcat:keyword "block-copolymer",
        "chemistry-of-polymers",
        "chimie-des-polymeres",
        "chimie-macromoleculaire",
        "chimie-supramoleculaire",
        "chimothechemical-sciencesother",
        "copolymere-a-bloc",
        "cyclodextrin",
        "cyclodextrine",
        "hydrogen-bond",
        "infoeu-reposemanticsdoctoralthesis",
        "liaison-hydrogene",
        "macromolecular-chemistry",
        "polymerisation-raft",
        "raft-polymerization",
        "supramolecular-chemistry",
        "theses" ;
    dcat:landingPage <https://theses.hal.science/tel-00735755> .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-tel-00735755v1/resource/de6eee04-478b-46a2-add0-3389d9db09e6> a dcat:Distribution ;
    dct:format "HTML" ;
    dct:issued "2026-11-01T20:34:56.142944"^^xsd:dateTime ;
    dct:modified "2026-11-01T20:34:55.949329"^^xsd:dateTime ;
    dct:title "Design of functionalized chain transfer agents, precursors to supramolecular copolymers based on H-bonding and host/guest inclusion" ;
    dcat:accessURL <https://theses.hal.science/tel-00735755> .

<https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> a foaf:Agent ;
    foaf:name "test_moissonnage_selune" .

<https://theses.hal.science/tel-00735755> a foaf:Document .