@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00945389v1> a dcat:Dataset ;
    dct:description """
              A key intermediate in the electroconversion of carbon dioxide to carbon monoxide, catalyzed by a manganese tris(carbonyl) complex, is characterized. Different catalytic pathways and their potential reaction mechanisms are investigated using a large range of experimental and computational techniques. Sophisticated spectroscopic methods including UV/Vis absorption and pulsed-EPR techniques (2P-ESEEM and HYSCORE) were combined together with DFT calculations to successfully identify a key intermediate in the catalytic cycle of CO<sub>2</sub> reduction. The results directly show the formation of a metal-carboxylic acid-CO<sub>2</sub> adduct after oxidative addition of CO<sub>2</sub> and H<sup>+</sup> to a Mn<sup>0</sup> carbonyl dimer, an unexpected intermediate.
            """ ;
    dct:identifier "hal-00945389" ;
    dct:issued "2026-05-06T17:35:10.006700"^^xsd:dateTime ;
    dct:language "en" ;
    dct:modified "2026-05-06T17:35:10.006705"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "Pulsed-EPR evidence of a manganese(II) hydroxycarbonyl intermediate in the electrocatalytic reduction of carbon dioxide by a manganese bipyridyl derivative" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
    dcat:distribution <https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00945389v1/resource/af01c343-7f19-4f00-a410-8110df36a30c> ;
    dcat:keyword "carbon-dioxide",
        "catalysis",
        "chimtheochemical-sciencestheoretical-andor-physical-chemistry",
        "electrocatalysis",
        "epr-spectroscopy",
        "infoeu-reposemanticsarticle",
        "journal-articles",
        "manganese" ;
    dcat:landingPage <ISSN:%201433-7851> .

<ISSN:%201433-7851> a foaf:Document .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00945389v1/resource/af01c343-7f19-4f00-a410-8110df36a30c> a dcat:Distribution ;
    dct:format "HTML" ;
    dct:issued "2026-05-06T17:35:10.016623"^^xsd:dateTime ;
    dct:modified "2026-05-06T17:35:09.992213"^^xsd:dateTime ;
    dct:title "Pulsed-EPR evidence of a manganese(II) hydroxycarbonyl intermediate in the electrocatalytic reduction of carbon dioxide by a manganese bipyridyl derivative" ;
    dcat:accessURL <https://hal.science/hal-00945389> .

<https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> a foaf:Agent ;
    foaf:name "test_moissonnage_selune" .