oai-hal-hal-00699818v1
type: Dataset
description: The polymerization of vinylic monomers such as DMAEMA ( 2-dimethyaminoethyl methacrylate) can be triggered electrochemically by an electrode and/or a solution electrogenerated reducer ( redox catalysis). The electrochemical mechanism is similar to that of other vinylic monomers. As the polymerization can be induced by redox catalysis, the DMAEMA polymerization can be transposed onto the n-doped poly( tetrafluoroethylene) ( PTFE) surfaces obtained by local scanning electrochemical microscopy reduction of PTFE. The copolymerization is evidenced by the ion-exchange properties of the obtained material. The amount of deposited polymeric material, of estimated width 50-150 nm, is related to the different experimental conditions. The mechanistic observations about the DMAEMA reduction allow a better insight into the PTFE reduction and subsequent DMAEMA copolymerization. It also nicely demonstrates that higher current densities are supported by microelectrode edges.
issued: 2026-05-17T18:40:37.309880
language: en
modified: 2026-05-17T18:40:37.309896
title: Surface modification of halogenated polymers. 10. Redox catalysis induction of the polymerization of vinylic monomers. Application to the localized graft copolymerization of poly(tetrafluoroethylene) surfaces by vinylic monomers
contact point: Organization
  fn: CCSD
keyword: acrylonitrile
keyword: aromatic-halides
keyword: chimanalchemical-sciencesanalytical-chemistry
keyword: chimmatechemical-sciencesmaterial-chemistry
keyword: electrogenerated-chemiluminescence
keyword: electropolymerization
keyword: feedback-mode
keyword: infoeu-reposemanticsarticle
keyword: journal-articles
keyword: methacrylonitrile
keyword: polytetrafluoroethylene-films
keyword: ptfe-films
keyword: reduction
keyword: scanning-electrochemical-microscopy
keyword: sduoceansciences-of-the-universe-physicsocean-atmosphere
landing page: 0897-4756

https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00699818v1/resource/d2d7850d-4b3c-4278-a625-dcb3b7402eec
type: Distribution
format: HTML
issued: 2026-05-17T18:40:37.327007
modified: 2026-05-17T18:40:37.249883
title: Surface modification of halogenated polymers. 10. Redox catalysis induction of the polymerization of vinylic monomers. Application to the localized graft copolymerization of poly(tetrafluoroethylene) surfaces by vinylic monomers
access URL: https://hal.science/hal-00699818

test_moissonnage_selune
type: Agent