@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00699818v1> a dcat:Dataset ;
    dct:description """
              The polymerization of vinylic monomers such as DMAEMA ( 2-dimethyaminoethyl methacrylate) can be triggered electrochemically by an electrode and/or a solution electrogenerated reducer ( redox catalysis). The electrochemical mechanism is similar to that of other vinylic monomers. As the polymerization can be induced by redox catalysis, the DMAEMA polymerization can be transposed onto the n-doped poly( tetrafluoroethylene) ( PTFE) surfaces obtained by local scanning electrochemical microscopy reduction of PTFE. The copolymerization is evidenced by the ion-exchange properties of the obtained material. The amount of deposited polymeric material, of estimated width 50-150 nm, is related to the different experimental conditions. The mechanistic observations about the DMAEMA reduction allow a better insight into the PTFE reduction and subsequent DMAEMA copolymerization. It also nicely demonstrates that higher current densities are supported by microelectrode edges.
            """ ;
    dct:identifier "hal-00699818" ;
    dct:issued "2026-05-17T18:40:37.309880"^^xsd:dateTime ;
    dct:language "en" ;
    dct:modified "2026-05-17T18:40:37.309896"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "Surface modification of halogenated polymers. 10. Redox catalysis induction of the polymerization of vinylic monomers. Application to the localized graft copolymerization of poly(tetrafluoroethylene) surfaces by vinylic monomers" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
    dcat:distribution <https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00699818v1/resource/d2d7850d-4b3c-4278-a625-dcb3b7402eec> ;
    dcat:keyword "acrylonitrile",
        "aromatic-halides",
        "chimanalchemical-sciencesanalytical-chemistry",
        "chimmatechemical-sciencesmaterial-chemistry",
        "electrogenerated-chemiluminescence",
        "electropolymerization",
        "feedback-mode",
        "infoeu-reposemanticsarticle",
        "journal-articles",
        "methacrylonitrile",
        "polytetrafluoroethylene-films",
        "ptfe-films",
        "reduction",
        "scanning-electrochemical-microscopy",
        "sduoceansciences-of-the-universe-physicsocean-atmosphere" ;
    dcat:landingPage <ISSN:%200897-4756> .

<ISSN:%200897-4756> a foaf:Document .

<https://rec.harvest-normandie.data4citizen.com/dataset/oai-hal-hal-00699818v1/resource/d2d7850d-4b3c-4278-a625-dcb3b7402eec> a dcat:Distribution ;
    dct:format "HTML" ;
    dct:issued "2026-05-17T18:40:37.327007"^^xsd:dateTime ;
    dct:modified "2026-05-17T18:40:37.249883"^^xsd:dateTime ;
    dct:title "Surface modification of halogenated polymers. 10. Redox catalysis induction of the polymerization of vinylic monomers. Application to the localized graft copolymerization of poly(tetrafluoroethylene) surfaces by vinylic monomers" ;
    dcat:accessURL <https://hal.science/hal-00699818> .

<https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> a foaf:Agent ;
    foaf:name "test_moissonnage_selune" .

