Preparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by Magnesium-Promoted Carbon-Chlorine Bond Activation
type: Dataset
description: Treatment of α-chloro-α,α-difluorotoluene and α-chloro-α,α-difluoroanisole with chlorotrimethylsilane in the presence of magnesium in DMF led to their corresponding trimethylsilyl derivatives. These compounds are able to transfer their fluorinated group to various electrophilic substrates (carbonyl compounds, disulfides, phenyl isocyanate).
landing page: 0936-5214
keyword: alkyl-halides
keyword: chimorgachemical-sciencesorganic-chemistry
keyword: fluorine
keyword: infoeu-reposemanticsarticle
keyword: journal-articles
keyword: magnesium
keyword: nucleophilic-additions
keyword: silicon
issued: 2026-05-06T05:48:31.283663
modified: 2026-05-06T05:48:31.283668
language: en
contact point: Organization
  fn: CCSD

test_moissonnage_selune
type: Agent

Preparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by Magnesium-Promoted Carbon-Chlorine Bond Activation
type: Distribution
format: HTML
access URL: https://hal.science/hal-00095222
issued: 2026-05-06T05:48:31.295286
modified: 2026-05-06T05:48:31.274149