Preparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by Magnesium-Promoted Carbon-Chlorine Bond Activation
type: Dataset
contact point: Organization
  fn: CCSD
keyword: alkyl-halides
keyword: journal-articles
keyword: magnesium
keyword: silicon
keyword: infoeu-reposemanticsarticle
keyword: nucleophilic-additions
keyword: fluorine
keyword: chimorgachemical-sciencesorganic-chemistry
landing page: 0936-5214
description: Treatment of α-chloro-α,α-difluorotoluene and α-chloro-α,α-difluoroanisole with chlorotrimethylsilane in the presence of magnesium in DMF led to their corresponding trimethylsilyl derivatives. These compounds are able to transfer their fluorinated group to various electrophilic substrates (carbonyl compounds, disulfides, phenyl isocyanate).
issued: 2026-05-06T05:48:31.283663
language: en
modified: 2026-05-06T05:48:31.283668

Preparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by Magnesium-Promoted Carbon-Chlorine Bond Activation
type: Distribution
access URL: https://hal.science/hal-00095222
format: HTML
issued: 2026-05-06T05:48:31.295286
modified: 2026-05-06T05:48:31.274149

test_moissonnage_selune
type: Agent