The “Building-Block” Assembly of a [Ni12Mn6] Aggregate
type: Dataset
description: Reaction of MnII(bdoa)(H2O)3 with Ni(CH3COO)2·3H2O in methanol gives a heterometallic cluster,[Ni12Mn6(bdoa)6- (O2CMe)12(μ3-OMe)12(MeOH)12]·21MeOH, which was structurally characterised by single-crystal X-ray diffraction and possesses three self-assembled tetranuclear nickel cubes connected by a MnII 6(bdoa)6(CH3COO)3 subunit. The magnetic properties were studied in detail and indicate that the compound possesses a high density of spin states with small energy gaps between them.
issued: 2026-05-07T08:58:10.214570
language: en
modified: 2026-05-07T08:58:10.214575
contact point: Organization
  fn: CCSD
keyword: carboxylate-ligands
keyword: chimmatechemical-sciencesmaterial-chemistry
keyword: cluster-compounds
keyword: cooperative-effects
keyword: infoeu-reposemanticsarticle
keyword: journal-articles
keyword: manganese
keyword: nickel
landing page: 1434-1948

The “Building-Block” Assembly of a [Ni12Mn6] Aggregate
type: Distribution
format: HTML
issued: 2026-05-07T08:58:10.216368
modified: 2026-05-07T08:58:10.206292
access URL: https://hal.science/hal-00093274

test_moissonnage_selune
type: Agent