@prefix dcat: <http://www.w3.org/ns/dcat#> .
@prefix dct: <http://purl.org/dc/terms/> .
@prefix foaf: <http://xmlns.com/foaf/0.1/> .
@prefix vcard: <http://www.w3.org/2006/vcard/ns#> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .

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    dct:description """
              Metalation of one aryl group of Ph3P=NR (R = methyl, isopropyl) affords an easy access to the corresponding lithium salt, which in turn reacts with chlorophosphines R2PCl (R = Ph, i-Pr) to yield a new class of bidentate ligand featuring one iminophosphorane and one phosphino group. Reaction of the phenyl derivative with [Pd(COD)Cl-2] yielded the expected six-membered palladacycle complex, which was structurally characterized. Extension of this new synthetic methodology toward the elaboration of enantiomerically pure tetradentate ligands has also been achieved.
            """ ;
    dct:identifier "hal-00090420" ;
    dct:issued "2026-05-08T06:13:45.550264"^^xsd:dateTime ;
    dct:language "en" ;
    dct:modified "2026-05-08T06:13:45.550269"^^xsd:dateTime ;
    dct:publisher <https://rec.harvest-normandie.data4citizen.com/organization/cce9db95-46d9-4dc2-84b6-764215d0a002> ;
    dct:title "Nitrogen-assisted ortho lithiation: One-pot synthesis of new classes of bidentate and tetradentate mixed P similar to N ligands" ;
    dcat:contactPoint [ a vcard:Organization ;
            vcard:fn "CCSD" ] ;
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    dcat:keyword "asymmetric-catalysis",
        "chimcoorchemical-sciencescoordination-chemistry",
        "coordination-",
        "hydrogenation-",
        "imine-ligands",
        "infoeu-reposemanticsarticle",
        "journal-articles",
        "palladium-complexes",
        "phosphine-" ;
    dcat:landingPage <ISSN:%200276-7333> .

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    dct:format "HTML" ;
    dct:issued "2026-05-08T06:13:45.552194"^^xsd:dateTime ;
    dct:modified "2026-05-08T06:13:45.533846"^^xsd:dateTime ;
    dct:title "Nitrogen-assisted ortho lithiation: One-pot synthesis of new classes of bidentate and tetradentate mixed P similar to N ligands" ;
    dcat:accessURL <https://hal.science/hal-00090420> .

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