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Geminal dianions as precursors for the synthesis of carbene complexes of tran...
Recently, a new method for the synthesis of carbene complexes of transition metal has been developed. The strategy consists in bringing the four electrons of the... -
Towards the synthesis of porphyrinic cages with a size-controlled cavity via ...
Covalent or coordination molecular cages are particularly interesting molecules when they incorporate an active cavity in molecular recognition or in chemical... -
Porphyrin-based [3]- and [4]rotaxanes : towards an adaptable molecular receptor
Rotaxanes and porphyrins are two particularly active fields of research in chemistry. However,molecules that combine the interesting properties of these types of... -
Combining Coordination Chemistry and Catalysis To Tie a Knot by an Active-Met...
International audience -
Hybrids ligands : synthesis and coordination chemistry
This manuscript deals with the synthesis of hybrids ligands and their coordination ability. The first part is dedicated to Cp-imidazole, Cp-imidazolium and... -
Synthesis and study of new di(heteroaryl)ethenes for optical commutation
This work deals with the synthesis and study of a new family of photochromic di(heteroaryl)ethenes as well as their use as bridging ligand in coordination chemistry in... -
Substitution-assisted stereochemical control of bispidone-based ligands.
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Molecular magnets based on polymetallic clusters : synthesis, crystal structu...
The Single-Molecule Magnets (SMMs) are polymetallic complexes containing unpaired electrons that have the remarkable property to behave individually as magnets.... -
The first hexadithienylethene-substituted tris(bipyridine)metal complexes as ...
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Design of photoactivable moleculars systems for solar energy conversion
This thesis is focussed on the development, optimisation and study of different molecular photocatalytic systems for the reduction of protons, in both organic solvents... -
Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes
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Electronic structure of bis-azepine transition-metal complexes: A DFT investi...
International audience -
The coordination of azepine to transition-metal complexes: A DFT analysis
International audience -
Acid-base-controlled stereoselective metalation of overhanging carboxylic Aci...
International audience -
From CO2 to dimethyl carbonate with dialkyldimethoxystannanes: the key role o...
International audience -
New functionalized β-diketiminate ligands and f elements
Β-Diketiminate ligands have received increased interest in coordination chemistry, especially for homogeneous catalysis. Their successful applications arise from an... -
Photo-induced spin crossover : synergy between stability and metastability
The study of spin crossover materials is an important challenge regarding their potentiality ininformation process, especially by optical way. Indeed, writing...
